Aquatic Chemistry and Thermodynamics of Actinides and long-lived Fission Products

The research of our group is dedicated to the investigation of the chemical behaviour of radionuclides in aqueous systems of relevance in the context of nuclear waste disposal. Main focus is on solubility phenomena of long-lived actinides and fission products like Pu, Np, U and Tc, i.e. on the equilibrium reactions between solubility-limiting radionuclide solid phases and the aqueous radionuclide species, including complexation with relevant ligands and redox reactions. The approach considered to tackle these complex systems strongly relies on classical solution chemistry methods (e.g., solubility experiments, absorption spectroscopy), in combination with solid phase characterization methods and advanced spectroscopic techniques such as time-resolved laser fluorescence spectroscopy (TRLFS) or X-ray absorption spectroscopy (XAFS). Our experimental studies are systematically performed as function of various solution parameters, in order to cover the geochemical boundary conditions expected for the different deep geological repository concepts. A specific research line is dedicated to the impact of elevated temperature conditions on the solution chemistry of radionuclides which may result from the decay of heat-generating nuclear waste in a repository. Our studies provide an adequate process understanding and thermodynamic description of the investigated radionuclide systems, including the evaluation of activity models (SIT, Pitzer). The corresponding data are the basis for thermodynamic databases and geochemical calculations, which play a key role in the long-term safety assessment of nuclear waste repositories.

Our research group also contributes to several national projects with focus on the interdisciplinary analyses of disposal options for radioactive waste in Germany (ENTRIA, funded by BMBF), providing support and expert judgement to BfS in the context of the Asse II salt mine, or participating in the development of the national thermodynamic reference database for actinides and fission products (THEREDA project). The expertise of our group in this field is further reflected in key contributions to highly relevant international projects, such as the OECD NEA–TDB thermodynamic series, the IUPAC Subcommittee on Solubility and Equilibrium Data, or the update of the Plutonium Handbook edited by the American Nuclear Society, among others. Our group has also on-going, long-lasting collaborations with research groups and waste management organizations world-wide.


Our group (as of 2017), from left to right: (top row) Alexander Baumann, Julian Schepperle, Nese Cevirim, Ezgi Yalcintas, Xavier Gaona, Melanie Böttle; (bottom row) Agost Tasi, Timo Schramm, Nicole Adam, Francesco Endrizzi, David Fellhauer. Jun-Yeop Lee is missing



Dr. Xavier Gaona     

    +49 721 608 26134

Aquatische Chemie 2
General view of the lab facilities and gloveboxes where the main research activities of the group are performed.
Aquatische Chemie 3
David Fellhauer and Julian Schepperle working at the neptunium glovebox.